Evidence for the formation of UO2(NO3)42- in an ionic liquid by EXAFS
Evidence for the formation of UO2(NO3)42- in an ionic liquid by EXAFS
Gaillard, C.; Klimchuk, O.; Ouadi, A.; Billard, I.; Hennig, C.
Abstract
The complexation between uranium(VI) and nitrate ions in a hydrophobic ionic liquid (IL), namely [BMI][NO3] (BMI = 1-butyl-3-methylimidazolium+), is investigated by EXAFS spectroscopy. It was performed by dissolution of uranyl nitrate UO2(NO3)2·6H2O or UO2(Tf2N)2 (Tf2N = bis(trifluoromethylsulfonyl) imide (CF3SO2)2N−). The formation of the complex UO2(NO3)4 2− is evidenced.
Keywords: EXAFS; UO2(NO3)42-; Ionic Liquids
Involved research facilities
- Rossendorf Beamline at ESRF DOI: 10.1107/S1600577520014265
Related publications
- DOI: 10.1107/S1600577520014265 is cited by this (Id 16861) publication
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Dalton Transactions 41(2012), 5476-5479
DOI: 10.1039/c2dt30205e
Cited 20 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-16861