Impact of Self-Trapped Excitons on Blue Photoluminescence in TiO2 Nanorods on Chemically Etched Si Pyramids
Impact of Self-Trapped Excitons on Blue Photoluminescence in TiO2 Nanorods on Chemically Etched Si Pyramids
Saini, C. P.; Barman, A.; Banerjee, D.; Grynko, O.; Prucnal, S.; Gupta, M.; Phase, D. M.; Sinha, A. K.; Kanjilal, D.; Skorupa, W.; Kanjilal, A.
Abstract
Temperature-dependent photoluminescence (PL) of titanium oxide (TiO2) shows an evolution of blue emission when exposed to 50 keV At+ ions. The origin of observed PL has been examined by X-ray absorption near-edge spectroscopy (XANES) at Ti-K,L and O-K edges, revealing the reduction of ligand field splitting owing to the formation of oxygen vacancies (OVs) by destroying TiO6 octahedral symmetry. Detailed PL and XANES analyses suggest that the fluence (ions/cm(2)) dependent increase in OVs not only boosts the conduction electrons but also increases the density of holes in localized self-trapped exciton (STE) states near the valence band. Based on these observations, we propose a model in which doped conduction electrons are recombining radiatively with the holes in STE states for blue light emission.
Keywords: titanium oxide; ion implantation; photoluminescence; X-ray absorption near-edge spectroscopy; oxygen vacancy; localized self-trapped exciton
Beteiligte Forschungsanlagen
- Ionenstrahlzentrum DOI: 10.17815/jlsrf-3-159
Verknüpfte Publikationen
- DOI: 10.17815/jlsrf-3-159 is cited by this (Id 25740) publication
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Journal of Physical Chemistry C 121(2017)21, 11448-11454
DOI: 10.1021/acs.jpcc.7b02218
ISSN: 1932-7455
Cited 41 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-25740