Publikationsrepositorium - Helmholtz-Zentrum Dresden-Rossendorf
1 PublikationNew Heterodinuclear Zn/Ln (Ln = Gd, Tb, Er, Yb) Complexes of Hexadentate N,N'-Bis(3-alkoxy-2-hydroxybenzyl)cyclohexane-1,2-diamines: Synthesis and Structure
Kelly, N.; Schnaars, K.; Gloe, K.; Doert, T.; Weigand, J. J.; Gloe, K.
Abstract
Two N,N′-bis(3-alkoxy-2-hydroxybenzyl)cyclohexane-1,2-diamine proligands, H₂L¹ (R = OCH₃) and H₂L² (R = OC₂H₅), and five heterodinuclear Znᴵᴵ/Lnᴵᴵᴵ complexes, [Zn(L)(µ-CH₃COO)Ln(NO₃)₂], containing [L¹]²⁻ and Gd³⁺, Tb³⁺, Er³⁺, or Yb³⁺ and [L²]²⁻ and Yb³⁺ have been synthesised and structurally characterised. The complexes are isostructural and crystallise in the P2₁/n monoclinic space group. Zinc(II) is coordinated by the inner N₂O₂ donor set of the ligand and an oxygen of the bridging acetate anion; the lanthanide(III) ions possess an O₉ coordination environment involving the interaction with the ligand’s outer O₄ donor set, two bidentate nitrate ions, and the bridging acetate.
-
Australian Journal of Chemistry 70(2017)5, 601-607
DOI: 10.1071/CH16716
Cited 3 times in Scopus
Permalink: https://www.hzdr.de/publications/Publ-27043