Antiferromagnetic resonance in the cubic iridium hexahalides (NH₄)₂IrCl₆ and K₂IrCl₆

We report on high-field electron spin resonance studies of two iridium hexahalide compounds (NH₄)₂IrCl₆ and K₂IrCl₆. In the paramagnetic state, our measurements reveal isotropic g factors g = 1.79(1) for the Ir⁴⁺ ions, in agreement with their cubic symmetries. Most importantly, in the magnetically ordered state, we observe two magnon modes with zero-field gaps of 11.3 and 14.2 K for (NH₄)₂IrCl₆ and K₂IrCl₆, respectively. Based on that and using linear spin-wave theory, we estimate the nearest-neighbor exchange couplings and anisotropic Kitaev interactions J₁/k_B = 10.3 K, K/k_B = 0.7 K for (NH₄)₂IrCl₆, and J₁/k_B = 13.8 K, K/k = 0.9 K for K₂IrCl₆, revealing the nearest-neighbor Heisenberg coupling as the leading interaction term, with only a weak Kitaev anisotropy.