Oxidation of Micro- and Nanograined UO2Pellets by in Situ Synchrotron X-ray Diffraction

When in contact with oxidising media, UO2 pellets used as nuclear fuel may transform into U4O9, U3O7, and U3O8. The latter starts forming by stress-induced phase transformation only upon cracking of the pristine U3O7, and is associated with a 36 % volumetric expansion with respect to the initial UO2. This may pose a safety issue for spent nuclear fuel (SNF) management as it could imply a confinement failure and hence dispersion of radionuclides within the environment. In this work, UO2 with different grain sizes (representative of the grain size in different radial positions in the SNF) were oxidised in air at 300 °C, and the oxidation mechanisms were investigated using in-situ synchrotron XRD. The formation of U3O8 was detected only in UO2 pellets with larger grains (3.08 ± 0.06 µm and 478 ± 17 nm), while U3O8 did not develop in sintered UO2 with a grain size of 163 ± 9 nm. This result shows that, in dense materials, a sufficiently fine microstructure inhibits both the cracking of U3O7 and the subsequent formation of U3O8. Hence, the nanostructure prevents the material from undergoing significant volumetric expansion. Considering that the peripheral region of SNF is constituted by the High Burnup Structure (HBS), characterised by 100-300 nm sized grains and micrometric porosity, these findings are relevant for a better understanding of the spent nuclear fuel behaviour and hence for the safety of the nuclear waste storage.