Epitaxial Stabilization of Perovskite ATeO3 Thin Films
Epitaxial Stabilization of Perovskite ATeO3 Thin Films
Herklotz, A.; Stefania Rus, F.; Koch, M. M.; Grove, K. M.; Bowen, M. S.; Cann, D. P.; Tippey, K. E.; Dörr, K.
Abstract
Tellurium oxides of the ATeO3 form typically do not crystallize in perovskite structures.
Here, we show that perovskite-like ATeO3 (A = Ca, Sr, Ba) thin films can be grown on perovskite
single-crystal substrates via epitaxial stabilization. These films are stable with high optical bandgaps,
low dielectric losses, and a high electric breakdown strength. Hysteretic dielectric behavior found
in SrTeO3 and BaTeO3 strongly suggests the presence of antiferroelectricity and ferroelectricity,
respectively. These properties make perovskite tellurium oxides possibly appealing candidates for
thin film coating or insulator materials in advanced microelectronics. Tellurium oxides constitute a
largely unexplored class of materials that might show new and interesting functionalities in epitaxial
thin-films. Our work encourages new work within this field.
Keywords: perovskite; ferroelectric; chalcogenide
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Coatings 13(2023)12, 2055
DOI: 10.3390/coatings13122055
Permalink: https://www.hzdr.de/publications/Publ-38389